potentially yes - there is a chance that the switch could be slightly slower than the sample and hold - in all likelihood it will be the other way round though - the answer is to experiment
if you find that you do have this issue then a trigger delay is the answer - either a dedicated one like the doepfer a-162 or in a more general module that can provide this functionality - you can create one in stages, for example
"some of the best base-level info to remember can be found in Jim's sigfile" @Lugia
Utility modules are the dull polish that makes the shiny modules actually shine!!!
sound sources < sound modifiers < modulation sources < utilities